1,4-THIOXANE
Base Information
- Chemical Name:1,4-THIOXANE
- CAS No.:15980-15-1
Chemical plants supply high-quality 1,4-THIOXANE 15980-15-1 in bulk
- Molecular Formula:C4H8OS
- Molecular Weight:104.173
- Appearance/Colour:clear colorless to yellow liquid
- Vapor Pressure:5.65mmHg at 25°C
- Melting Point:-17°C
- Refractive Index:n20/D 1.5095(lit.)
- Boiling Point:147.2 °C at 760 mmHg
- Flash Point:55.6 °C
- PSA:34.53000
- Density:1.074 g/cm3
- LogP:0.74980
1,4-THIOXANE(Cas 15980-15-1) Usage
|
Safety Profile |
Moderately toxic by ingestion. Mildly toxic by inhalation. A skin and eye irritant. Flammable liquid when exposed to heat, sparks,flame, or oxidizers. Forms explosive complexes with silver perchlorate or copper(I) perchlorate. Incompatible with metal perc |
|
General Description |
1,4-Thioxane is identified as a major product of the thermal degradation of sulfur mustard (HD) in the presence of certain metal oxide adsorbents, including Zr(OH)4, Al2O3, Al2CoO4, and CeO2. Its formation highlights its role as a stable cyclic compound derived from the breakdown of HD under thermal conditions, particularly when catalyzed by these oxides. Notably, Zr(OH)4 significantly enhances this degradation process. |
InChI:InChI=1/C4H8OS/c1-3-6-4-2-5-1/h1-4H2
15980-15-1 Relevant articles
Reactions of bielectrophiles (ClCH2CH2)2Y with sulfur in basic reducing systems
Korchevin,Russavskaya,Alekminskaya,Deryagina
, p. 240 - 243 (2002)
A simple procedure was developed for pre...
Enhanced thermal degradation of 2,2′-dichlorodiethyl sulfide (sulfur mustard, HD) with the presence of metal oxides
Jung, Hyunsook,Lee, Hae Wan,Jeong, Eun Ah
, p. 1137 - 1141 (2016)
Thermal degradation of sulfur mustard (2...
-
Georgieff,Dupre
, p. 1104,1107 (1959)
-
Destruction of chemical warfare agent simulants by air and moisture stable metal NHC complexes
Weetman, Catherine,Notman, Stuart,Arnold, Polly L.
supporting information, p. 2568 - 2574 (2018/02/28)
The cooperative effect of both NHC and m...
Degradation of Sulfur Mustard on KF/Al2O3: The Role of Organic Solvents and Active Species
Fridkin, Gil,Columbus, Ishay,Yehezkel, Lea,Zafrani, Yossi
, p. 10541 - 10545 (2018/07/25)
Solvent effects on the ability of KF/Al2...
Synthesis of cyclic ethers from diols in the presence of copper catalysts
Bayguzina,Gimaletdinova,Khusnutdinov
, p. 1840 - 1843 (2018/02/06)
A number of cyclic ethers, namely tetrah...
Metal ferrite nanoparticles: Synthesis, characterization, and studies on decontamination of sulfur mustard
Praveen Kumar,Prasad,Ramacharyulu,Singh, Beer,Anchal Roy
, p. 833 - 840 (2016/09/28)
Mg, Ca, Mn, Co, Ni, Cu, Zn, Mn-Zn, and C...
15980-15-1 Process route
-
-
7783-06-4
hydrogen sulfide
-
-
107-21-1
ethylene glycol
-
-
497-26-7
2-methyl-1,3-dioxolane
-
-
123-91-1,28347-88-8,28347-91-3,39449-24-6,54841-74-6
1,4-dioxane
-
-
15980-15-1
1,4-Oxathiane
-
-
75-07-0,9002-91-9
acetaldehyde
| Conditions | Yield |
|---|---|
|
at 225 ℃;
Produkt 5:<1,4>Dithian;
|
-
-
505-60-2
bis (2-chloroethyl) sulphide
-
-
15980-15-1
1,4-Oxathiane
-
-
505-29-3
1,4-Dithiane
-
-
81142-02-1
β-chloroethyl vinyl sulfide
-
-
3090-56-0
2-hydroxyethyl vinyl sulfide
| Conditions | Yield |
|---|---|
|
With
zirconium tetrahydroxide;
at 20 - 100 ℃;
for 6h;
Reagent/catalyst;
Sealed tube;
|
15980-15-1 Upstream products
-
75-21-8
oxirane
-
111-48-8
2,2'-thiobis-ethanol
-
693-30-1
mustard chlorohydrin
-
64-17-5
ethanol
15980-15-1 Downstream products
-
85-47-2
1-naphthalenesulfonic acid
-
98019-94-4
2,3-dichloro-[1,4]oxathiane
-
107-61-9
1,4-oxathiane-4,4-dioxide
-
6538-93-8
5,6-dihydro-1,4-oxathiine
Product recommendations
- 3-(o-tolylazo)toluene-2,6-diamine monoacetate
- 1-(4-fluorophenyl)-1,3-dihydro-1-[3-(methylamino)propyl]isobenzofuran-5-carbonitrile
- 4-(2-carboxyindol-3-yl)butyric acid
- 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecanesulphonyl chloride
- TRANS-2-OCTENOIC ACID
- trisodium 4-[[6-[[4-chloro-6-(methylphenylamino)-1,3,5-triazin-2-yl]amino]-1-hydroxy-3-sulphonato-2-naphthyl]azo]toluene-2,5-disulphonate
- 3-(9,10-Ethano-9(10H)-anthryl)acrylaldehyde
- 9-ETHYL-3-(N-METHYL-N-PHENYLHYDRAZONOMETHYL)CARBAZOLE
