2-benzyl-4-methylpyridine

Base Information

  • Chemical Name: 2-benzyl-4-methylpyridine
  • CAS No.: 5191-54-8

Bulk supply high purity 2-benzyl-4-methylpyridine 5191-54-8, Paid sample available

  • Molecular Formula: C13H13 N
  • Molecular Weight: 183.253
  • Vapor Pressure: 0.00378mmHg at 25°C 
  • Boiling Point: 289.6°C at 760 mmHg 
  • Flash Point: 120°C 
  • PSA: 12.89000 
  • Density: 1.027g/cm3 
  • LogP: 2.98080 

2-benzyl-4-methylpyridine(Cas 5191-54-8) Usage

InChI:InChI=1/C13H13N/c1-11-7-8-14-13(9-11)10-12-5-3-2-4-6-12/h2-9H,10H2,1H3

5191-54-8 Relevant articles

Acylation of 2-benzylpyridine N-oxides and subsequent in situ [3,3]-sigamatropic rearrangement reaction

Antilla, Jon C.,Jing, Hua-qing,Li, Hong-liang

supporting information, (2020/09/22)

An effective method for the acylation of...

Catalytic Selective Metal-Free Cross-Coupling of Heteroaromatic N-Oxides with Organosilanes

Puthanveedu, Mahesh,Polychronidou, Vasiliki,Antonchick, Andrey P.

supporting information, p. 3407 - 3411 (2019/05/10)

A metal-free, regioselective C-H functio...

Photocatalyzed ortho-Alkylation of Pyridine N-Oxides through Alkene Cleavage

Zhou, Wang,Miura, Tomoya,Murakami, Masahiro

supporting information, p. 5139 - 5142 (2018/05/30)

A photocatalyzed reaction of pyridine N-...

Palladium-Catalyzed Arylation of Benzylic C-H Bonds of Azaarylmethanes with Aryl Sulfides

Gao, Ke,Yamamoto, Keita,Nogi, Keisuke,Yorimitsu, Hideki

supporting information, p. 2956 - 2960 (2017/10/06)

Benzylic C-H arylation of azaarylmethane...

5191-54-8 Process route

2,4-lutidine
108-47-4

2,4-lutidine

methyl-phenyl-thioether
100-68-5

methyl-phenyl-thioether

2-benzyl-4-methyl pyridine
5191-54-8

2-benzyl-4-methyl pyridine

4-benzyl-2-methylpyridine
7300-29-0

4-benzyl-2-methylpyridine

Conditions
Conditions Yield
With SingaCycle-A3; potassium hexamethylsilazane; In octane; at 100 ℃; for 12h; Inert atmosphere;
34%
50%
2-Bromo-4-picoline
4926-28-7

2-Bromo-4-picoline

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

2-benzyl-4-methyl pyridine
5191-54-8

2-benzyl-4-methyl pyridine

Conditions
Conditions Yield
benzylmagnesium chloride; With cobalt acetylacetonate; In tetrahydrofuran; 1,4-dioxane; at 0 - 25 ℃; for 0.0833333h; Inert atmosphere;
2-Bromo-4-picoline; In tetrahydrofuran; 1,4-dioxane; at 25 ℃; for 2h; Inert atmosphere;

5191-54-8 Upstream products

  • 23662-66-0
    23662-66-0

    1-benzyl-4-methylpyridinium chloride

  • 80772-88-9
    80772-88-9

    2-benzyl-4-methylpyridine 1-oxide

  • 94892-46-3
    94892-46-3

    2-Benzyl-1,4-dimethyl-pyridinium; iodide

  • 4926-28-7
    4926-28-7

    2-Bromo-4-picoline

5191-54-8 Downstream products

  • 25927-45-1
    25927-45-1

    2-(2,4-dinitrobenzyl)-4-methylpyridine

  • 1581709-76-3
    1581709-76-3

    4-methyl-2-(1-phenylvinyl)pyridine

  • 1581709-77-4
    1581709-77-4

    2-(1-phenylvinyl)-4-vinylpyridine

  • 80772-88-9
    80772-88-9

    2-benzyl-4-methylpyridine 1-oxide

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