.png)
4-Fluorobenzyl mercaptan
Base Information
- Chemical Name: 4-Fluorobenzyl mercaptan
- CAS No.: 15894-04-9
Reputable factory supply 4-Fluorobenzyl mercaptan 15894-04-9 in stock with high standard
- Molecular Formula: C7H7FS
- Molecular Weight: 142.197
- Vapor Pressure: 0.00502mmHg at 25°C
- Refractive Index: n20/D 1.545(lit.)
- Boiling Point: 201.994 °C at 760 mmHg
- PKA: 9.53±0.10(Predicted)
- Flash Point: 76.274 °C
- PSA： 38.80000
- Density: 1.147 g/cm3
- LogP: 2.25550
4-Fluorobenzyl mercaptan(Cas 15894-04-9) Usage
|
General Description |
4-Fluorobenzyl mercaptan undergoes reaction with p-chloranil to afford mainly 2,5-dichloro-3,6-S-disubstituted benzoquinone and 2,6-dichloro-3,5-S-disubstituted benzoquinone. |
InChI:InChI=1/C10H8FNO/c1-6-4-10(13)8-5-7(11)2-3-9(8)12-6/h2-5H,1H3,(H,12,13)
15894-04-9 Relevant articles
Reactions of Arylmethanethiols with 1,4-Disubstituted 1,3-Butadiynes
Freeman, Fillmore,Lu, Hengyao,Zeng, Qingbei
, p. 4350 - 4354 (1994)
-
Nonenzymatic Dynamic Kinetic Resolution of in situ Generated Hemithioacetals: Access to 1,3-Disubstituted Phthalans
Nath, Utpal,Chowdhury, Deepan,Pan, Subhas Chandra
supporting information, p. 1628 - 1633 (2018/03/21)
The first nonenzymatic DKR reaction of h...
Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols
Maurya, Chandra Kant,Mazumder, Avik,Gupta, Pradeep Kumar
supporting information, p. 1184 - 1188 (2017/07/03)
In this paper we report an efficient and...
Phosphorus Pentasulfide Mediated Conversion of Primary Carbamates into Thiols
Maurya, Chandra Kant,Gupta, Pradeep Kumar
, p. 1649 - 1651 (2017/08/11)
In this paper, we report a method for th...
Preparation and in-vitro evaluation of 4-benzylsulfanylpyridine-2- carbohydrazides as potential antituberculosis agents
Herzigova, Petra,Klimesova, Vera,Palat, Karel,Kaustova, Jarmila,Dahse, Hans-Martin,Moellmann, Ute
body text, p. 394 - 404 (2009/11/30)
A set of 4-benzylsulfanylpyridine-2-carb...
15894-04-9 Process route
-
-
1-Fluoro-4-octylsulfanylmethyl-benzene
-
-
352-32-9
p-fluorotoluene
-
-
111-88-6
Octanethiol
-
-
111-66-0,25068-25-1
oct-1-ene
-
-
458-76-4
4,4'-difluorobibenzyl
-
-
15894-04-9
(4-fluorophenyl)methanethiol
-
-
1-fluoro-4-nonylbenzene
| Conditions | Yield |
|---|---|
|
With
hydrogen;
In
acetone;
at -78 ℃;
for 0.25h;
under 3.5 Torr;
Mechanism;
Product distribution;
other alkyl substituted-benzyl sulfides and alkyl sulfides, competition with n-octyl benzyl sulfide, reaction rate relative to n-octyl benzyl sulfide, microwave generation of H from H2;
|
0.12 % Chromat.
0.77 % Chromat. 3.60 % Chromat. 1.03 % Chromat. 14.3 % Chromat. |
-
-
2740-87-6
p-fluorobenzyl thiocyanate
-
-
15894-04-9
(4-fluorophenyl)methanethiol
| Conditions | Yield |
|---|---|
|
With
tetraphosphorus decasulfide;
In
toluene;
for 3h;
Reflux;
|
75%
|
15894-04-9 Upstream products
-
459-46-1
4-Fluorobenzyl bromide
-
459-56-3
4-fluorobenzylic alcohol
-
352-11-4
1-chloromethyl-4-fluorobenzene
-
98-16-8
3-trifluoromethylaniline
Product recommendations
- 2-(8-heptadecenyl)-4,5-dihydro-1-methyl-1-[2-[(1-oxo-9-octadecenyl)amino]ethyl]-1H-imidazolium methyl sulphate
- N,N-DIETHYL-P-PHENYLENEDIAMINE MONOHYDROCHLORIDE
- 1,3,5,7-tetraacetyloctahydro-1,3,5,7-tetrazocine
- 2-benzyl-4-methylpyridine
- 3-[4-(diethylamino)phenyl]-3-(p-tolyl)phthalide
- 4'-CHLOROACETANILIDE
- sodium 7-[(4-aminobenzoyl)amino]-4-hydroxynaphthalene-2-sulphonate
- 2,4-dicyclopentyl-6-isopropyl-m-cresol